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31.15

Hoá lý

Hoàng Thị Hương Huế, Đào Ngọc Nhiệm(1)

Đặc trưng và hoạt tính xúc tác cho phản ứng oxi hóa CO của các oxit CuO, CeO2 và oxit hỗn hợp CuO-CeO2

Characteristics and catalytic activity of CuO, CeO2 oxides and CuO-CeO2 mixed oxide for CO oxidation

Hóa học

2014

1

86-90

0866-7144

CuO-CeO2 mixed oxide with 7.5 percent CuO content prepared by co-precipitation method, has been tested for the oxidation of CO conditions at 30-327°C. Catalysts have been characterized by means of X-ray diffraction (XRD), H2-temperature-programmed reduction (H2-TPR) and Raman spectroscopy. H2-TPR results indicated that there are three CuO species in the mixed oxide: the Cu2+ mostly exists in the bulk CuO and the left in CuxCe1-xO2 solid solution and finely dispersed CuO species on the surface of CeO2. The calculating results of the oxygen vacancy concentration in CuO-CeO2 mixed oxide from Gaussian deconvolution of Raman spectra showed that, oxygen vacancy concentration in CuO-CeO2 mixed oxide was 4.5 percent. Investigated catalytic possibility of CuO, CeO2 and CuO-CeO2 mixed oxide in transformation of CO. The results showed that, CuO-CeO2 mixed oxide has higher catalytic activity compared CuO and CeO2 oxides. The synergistic interaction between CuO and CeO2 is the main factor responsible for high catalytic activity of CuO-CeO2 mixed oxide. At ambient temperature (30°C), yield of CO treatment of CuO-CeO2 mixed oxide was relatively high (53.2 percent) and the transformation of CO almost finished at the temperature 207°C (98.4 percent).

TTKHCNQG, CVv 14