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31.15

10403 - Hoá lý

Đặc trưng và hoạt tính xúc tác cho phản ứng oxi hóa CO của các oxit CuO, CeO2 và oxit hỗn hợp CuO-CeO2

Characteristics and catalytic activity of CuO, CeO2 oxides and CuO-CeO2 mixed oxide for CO oxidation

Hóa học

2014

1

86-90

0866-7144

CuO-CeO2 mixed oxide with 7.5 percent CuO content prepared by co-precipitation method, has been tested for the oxidation of CO conditions at 30-327°C. Catalysts have been characterized by means of X-ray diffraction (XRD), H2-temperature-programmed reduction (H2-TPR) and Raman spectroscopy. H2-TPR results indicated that there are three CuO species in the mixed oxide: the Cu2+ mostly exists in the bulk CuO and the left in CuxCe1-xO2 solid solution and finely dispersed CuO species on the surface of CeO2. The calculating results of the oxygen vacancy concentration in CuO-CeO2 mixed oxide from Gaussian deconvolution of Raman spectra showed that, oxygen vacancy concentration in CuO-CeO2 mixed oxide was 4.5 percent. Investigated catalytic possibility of CuO, CeO2 and CuO-CeO2 mixed oxide in transformation of CO. The results showed that, CuO-CeO2 mixed oxide has higher catalytic activity compared CuO and CeO2 oxides. The synergistic interaction between CuO and CeO2 is the main factor responsible for high catalytic activity of CuO-CeO2 mixed oxide. At ambient temperature (30°C), yield of CO treatment of CuO-CeO2 mixed oxide was relatively high (53.2 percent) and the transformation of CO almost finished at the temperature 207°C (98.4 percent).

TTKHCNQG, CVv 14