BỘ KHOA HỌC VÀ CÔNG NGHỆ
HỆ THỐNG THÔNG TIN KHOA HỌC VÀ CÔNG NGHỆ

Lọc theo danh mục
  • Năm xuất bản
    Xem thêm
  • Lĩnh vực
liên kết website
Lượt truy cập
 Lượt truy cập :  28,177,619
  • Công bố khoa học và công nghệ Việt Nam

Kỹ thuật môi trường và địa chất, địa kỹ thuật

Phạm Tăng Cát Lượng, Lưu Gia Hy, Trương Chí Hiền, Nguyễn Kim Diễm Mai(1)

Nghiên cứu khả năng xử lí ion Pb(ii) và Cu(ii) trong dung dịch bằng than sinh học điều chế từ mùn cưa

A study on the removal of ions pb(ii) and cu(ii) from solution by using biochar derived from sawdust

Tạp chí Khoa học - Đại học Sư phạm TP Hồ Chí Minh

2021

12

2162-2177

1859-3100

Hấp phụ, Than sinh học, Cu(II), Pb(II), Mùn cưa, Nước thải

adsorption, biochar, Cu(II), Pb(II), sawdust, wastewater

Bài báo này khảo sát các yếu tố tác động đến quá trình hấp phụ ion Pb(II) và Cu(II) trên vật liệu than sinh học điều chế từ mùn cưa. Các yếu tố khảo sát bao gồm: giá trị pH (2,0-6,0), nồng độ ion kim loại (5-200 mg‧L-1), thời gian hấp phụ (5-1440 phút), khối lượng than sinh học (0,05-0,10g). Kết quả cho thấy dung lượng hấp phụ cực đại đạt 62,11 mg‧g-1 đối với Pb(II) và 20,49 mg‧g-1 đối với Cu(II) ở pH = 4,0 và thời gian đạt cân bằng hấp phụ là 120 phút. Quá trình hấp phụ ion Pb(II) và Cu(II) trên than sinh học phù hợp hơn với quy luật động học bậc hai và mô hình đẳng nhiệt hấp phụ Langmuir. Nghiên cứu này cũng công bố kết quả xử lí ion Pb(II) và Cu(II) trong nước thải ở Phòng Thí nghiệm Hóa Vô cơ, Trường Đại học Sư phạm Thành phố Hồ Chí Minh.

This study aims to investigate four factors affecting the adsorption process of Pb(II) and Cu(II) ions on biochar prepared from sawdust. These factors include: pH (2.0-6.0), metal ion concentration (5-200 mg.L-1), adsorption time (5-1440 minutes), and biochar weight (0.05-0.10 g). The results show that the maximum amount of metal ion adsorbed per adsorbent mass unit reached 62.11 mg.g-1 for Pb(II) and 20.49 mg.g-1 for Cu(II) at pH = 4.0 and adsorption time of 120 minutes. The adsorption of Pb(II) and Cu(II) ions on biochar is well represented by the second-order kinetics and Langmuir adsorption isotherm model. This study presents the ability to remove Pb(II) and Cu(II) ions in wastewater of the Inorganic Chemistry laboratory at Ho Chi Minh City University of Education

TTKHCNQG, CTv 138

Xem toàn văn
  • [1] Yurekli, Y. (2016), Removal of heavy metals in wastewater by using zeolite nano-particles impregnated polysulfone membranes.,Journal of Hazardous Materials, 309, 53-64. https://doi.org/10.1016/j.jhazmat.2016.01.064
  • [2] Xue, C., Zhu, L., Lei, S., Liu, M., Hong, C., Che, L., Wang, J., & Qiu, Y. (2020), Lead competition al-ters the zinc adsorption mechanism on animal-derived bioc-har.,Science of the Total Environment, 713, 136395. https://doi.org/10.1016/j.scitotenv.2019.136395
  • [3] Wu, Q., Xian, Y., He, Z., Zhang, Q., Wu, J., Yang, G., Zhang, X., Qi, H., Ma, J., Xiao, Y., & Long, L. (2019), Adsorption c-haracteristics of Pb(II) using bioc-har derived f-rom spent mushroom substrate.,Scientific Reports, 9(1), 1-11. https://doi.org/10.1038/s41598-019-52554-2
  • [4] Wani, A. L., Ara, A., & Usmani, J. A. (2015), Lead toxicity: A review,Interdisciplinary Toxicology, 8(2), 55-64. https://doi.org/10.1515/intox-2015-0009
  • [5] Wang, Y., Liu, Y., Lu, H., Yang, R., & Yang, S. (2018), Competitive adsorption of Pb (II), Cu (II), and Zn ( II ) ions onto hydroxyapatite-bioc-har nanocomposite in aqueous solutions.,Journal of Solid State Chemistry, 261(February), 53-61. https://doi.org/10.1016/j.jssc.2018.02.010
  • [6] Shen, Z., Hou, D., Jin, F., Shi, J., Fan, X., Tsang, D. C. W., & Alessi, D. S. (2019), Effect of production temperature on lead removal mechanisms by rice straw bioc-hars,Science of the Total Environment, 655, 751-758. https://doi.org/10.1016/j.scitotenv.2018.11.282
  • [7] Pellera, F., Giannis, A., Kalderis, D., Anastasiadou, K., Stegmann, R., Wang, J., & Gidarakos, E. (2012), Adsorption of Cu ( II ) ions f-rom aqueous solutions on bioc-hars prepared f-rom agricultural by-products.,Journal of Environmental Management, 96(1), 35-42. https://doi.org/10.1016/j.jenvman.2011.10.010
  • [8] Oliveira, W. E., Franca, A. S., Oliveira, L. S., & Rocha, S. D. (2008), Untreated coffee husks as biosorbents for the removal of heavy metals f-rom aqueous solutions,Journal of Hazardous Materials, 152(3), 1073-1081. https://doi.org/10.1016/j.jhazmat.2007.07.085
  • [9] Nguyen, V. P., Le, T. T. T., Nguyen, T. C. N., Nguyen, T. L., & Lam, T. M. N. (2020), Danh gia kha nang hap phu Pb2+ trong nuoc cua than sinh hoc có nguon goc tu phan bo [Assessment of Pb2+ absorption capacity in water of cow manure derived bioc-har].,Journal of Science Technology & Food, 20(1), 76-86.
  • [10] Merck. (2021), IR Spectrum Table & C-hart.,Retrieved f-rom https://www.sigmaaldrich.com/VN/en/technical-documents/technical-article/analyticalchemistry/photometry-and-reflectometry/ir-spectrum-table#ir-table-by-compound
  • [11] Ma, J., Huang, W., Li, Y., & Wang, N. (2020), Journal of Environmental Chemical Engineering The utilization of lobster shell to prepare low-cost bioc-har for high-efficient removal of copper and cadmium f-rom aqueous : Sorption properties and mechanisms.,Journal of Environmental Chemical Engineering, August, 104703. https://doi.org/10.1016/j.jece.2020.104703
  • [12] Liu, W. J., Jiang, H., & Yu, H. Q. (2015), Development of Bioc-har-Based Functional Materials: Toward a Sustainable Platform Carbon Material.,Chemical Reviews, 115(22), 12251-12285. https://doi.org/10.1021/acs.chemrev.5b00195
  • [13] Kiliç, M., Kirbiyik, Ç., Çepelioǧullar, Ö., & Pütün, A. E. (2013), Adsorption of heavy metal ions f-rom aqueous solutions by bio-c-har, a by-product of pyrolysis,Applied Surface Science, 283, 856-862. https://doi.org/10.1016/j.apsusc.2013.07.033
  • [14] Jamshidifard, S., Koushkbaghi, S., Hosseini, S., Rezaei, S., Karamipour, A., Jafari rad, A., & Irani, M. (2019), Incorporation of UiO-66-NH2 MOF into the PAN/chitosan nanofibers for adsorption and membrane filtration of Pb(II), Cd(II) and Cr(VI) ions f-rom aqueous solutions.,Journal of Hazardous Materials, 368(October 2018), 10-20. https://doi.org/10.1016/j.jhazmat.2019.01.024
  • [15] Inyang, M., Gao, B., Yao, Y., Xue, Y., & Zimmerman, A. R. (2012), Bioresource Technology Removal of heavy metals f-rom aqueous solution by bioc-hars derived f-rom anaerobically digested biomass.,Bioresource Technology, 110, 50-56. https://doi.org/10.1016/j.biortech.2012.01.072
  • [16] Han, L., Sun, H., Ro, K. S., Sun, K., Libra, J. A., & Xing, B. (2017), Removal of antimony (III) and cadmium (II) f-rom aqueous solution using animal manure-derived hydroc-hars and pyroc-hars.,Bioresource Technology, 234(Iii), 77-85. https://doi.org/10.1016/j.biortech.2017.02.130
  • [17] Feng, N., Guo, X., Liang, S., Zhu, Y., & Liu, J. (2011), Biosorption of heavy metals f-rom aqueous solutions by chemically modified orange peel.,Journal of Hazardous Materials, 185(1), 49–54. https://doi.org/10.1016/j.jhazmat.2010.08.114
  • [18] Dang, X. T., Dang, T. D., & Tran, T. K. L. (2016), Xac dinh ham luong Cu, Pb, Cd, Mn trong mau nuoc thai sinh hoat khu vuc Thach Son - Lam Thao – Phu Tho bang phuong phap pho hap thu nguyen tu [Determining the amount of Cu, Pb, Cd, Mn in water and waste water in Thach SonLam Thao-Phu Tho by F-AAS method].,Ho Chi Minh City University of Education Journal of Science, 43-52.
  • [19] Chi, T., Zuo, J., & Liu, F. (2017), Performance and mechanism for cadmium and lead adsorption f-rom water and soil by corn straw bioc-har.,Frontiers of Environmental Science and Engineering, 11(2). https://doi.org/10.1007/s11783-017-0921-y
  • [20] Chen, Y., Wang, C., & Wang, Z. (2005), Residues and source identification of persistent organic pollutants in farmland soils irrigated by effluents f-rom biological treatment plants.,Environment International, 31(6), 778-783. https://doi.org/10.1016/j.envint.2005.05.024
  • [21] Bui, V. T., & Tran, T. X. M. (2017), Khao sat hap phu As(V) trong dung dich nuoc bang vat lieu zeolite bien tinh bang Mn [Investigating the As(V) ions removal in aqueous solution using Mn-Modifed zeolite material].,Dong Thap University Journal of Science, 24(2017), 76-82.
  • [22] Bakatula, E. N., Ric-hard, D., Neculita, C. M., & Zagury, G. J. (2018), Determination of point of zero c-harge of natural organic materials,Environmental Science and Pollution Research, 25(8), 7823-7833. https://doi.org/10.1007/s11356-017-1115-7
  • [23] Atkins, P. W. (Chief Editor), & De, P. J. (Editor) (2013), Physical chemistry,
  • [24] Abdul, G., Zhu, X., & Chen, B. (2017), Structural c-haracteristics of bioc-har-graphene nanosheet composites and their adsorption performance for phthalic acid esters.,Chemical Engineering Journal, 319, 9-20. https://doi.org/10.1016/j.cej.2017.02.074
  • [25] Abdolali, A., Ngo, H. H., Guo, W., Lu, S., Chen, S. S., Nguyen, N. C., Zhang, X., Wang, J., & Wu, Y. (2016), A breakthrough biosorbent in removing heavy metals: Equilibrium, kinetic, thermodynamic and mechanism analyses in a lab-scale study.,Science of the Total Environment, 542, 603-611. https://doi.org/10.1016/j.scitotenv.2015.10.095