The study aims to demonstrate the impact of barriers on students’ intention to use mobile paymentservices in Hanoi. Barriers are divided into two groups, functional barriers and psychological barriers, whichplay an important role in shaping innovative decisions in students’ behaviors. The study was conducted byonline survey from 387 university students in Hanoi city used for analysis, then the collected data used toanalyze and test the hypotheses proposed in the study by Smart PLS 3.1 software with PLS-SEM analysismethod. The results show that usage barriers, value barriers, risk barriers and traditional barriers have anegative impact on the intention to use mobile payment services. While, there is no evidence to prove therelationship between image barrier and intention to use mobile payment service of Hanoi students. Basedon the research results, the author proposes a number of recommendations to promote the intention to usemobile payment services, contributing to attracting and developing the application of services using newtechnologies in transactions.