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Trương Anh Khoa, Lê Thị Nhung, Phan Minh Phương, Phạm Đức Thịnh(1), Nguyễn Ngọc Linh, Nguyễn Thị Thu Hương, Nguyễn Hoàng

ẢNH HƯỞNG CỦA Zn ĐẾN ĐẶC TÍNH ĐIỆN HÓA VÀ KHẢ NĂNG CHỐNG HÀ CỦA LỚP PHỦ ETHYL SILICATE

EFFECT OF Zn ON ELECTROCHEMICAL PROPERTIES AND ANTI-FOULING ABILITY OF ETHYL SILICATE COATINGS

Tạp chí Phân tích Hóa, Lý và Sinh học

2024

2A

126

Traditional antifouling coatings include paint layers: anti-corrosion primer, intermediate paint and antifouling paint. To overcome the difficulty of bonding between paint layers, a coating that integrates antifouling and anti-corrosion capabilities in the same coating on an ethyl silicate binder has been researched. In the pigment mixture including spherical Zn, flake ZnAl and Cu2O, the effect of spherical Zn content (30 wt%, 40 wt% and 50 wt%) on anti-corrosion properties was investigated by electrochemical impedance spectroscopy and polarization curves. The results after 30 days of soaking in 3.5 wt% NaCl showed that the total resistance of the coatings increased, and the corrosion resistance of the coating with 50 wt% Zn content reached the highest efficiency, the impedance module reaches the value 50,2 kΩ.cm2. The polarization curve method also confirmed the corrosion protection of the integrated coatings following a cathodic protection mechanism. Antifouling test results in natural seawater environment after 2 months of testing showed that, with appropriate Zn content (30 wt% Zn), an integrated coating with the lowest fouling density was created in the research samples, the coating surface only shows a biofouling film, the surface is still visible under the fouling layer%. Test results show that the integrated coating has the ability to prevent settlement and inhibit the growth of marine microorganisms for 2 months.

Traditional antifouling coatings include paint layers: anti-corrosion primer, intermediate paint and antifouling paint. To overcome the difficulty of bonding between paint layers, a coating that integrates antifouling and anti-corrosion capabilities in the same coating on an ethyl silicate binder has been researched. In the pigment mixture including spherical Zn, flake ZnAl and Cu2O, the effect of spherical Zn content (30 wt%, 40 wt% and 50 wt%) on anti-corrosion properties was investigated by electrochemical impedance spectroscopy and polarization curves. The results after 30 days of soaking in 3.5 wt% NaCl showed that the total resistance of the coatings increased, and the corrosion resistance of the coating with 50 wt% Zn content reached the highest efficiency, the impedance module reaches the value 50,2 kΩ.cm2. The polarization curve method also confirmed the corrosion protection of the integrated coatings following a cathodic protection mechanism. Antifouling test results in natural seawater environment after 2 months of testing showed that, with appropriate Zn content (30 wt% Zn), an integrated coating with the lowest fouling density was created in the research samples, the coating surface only shows a biofouling film, the surface is still visible under the fouling layer%. Test results show that the integrated coating has the ability to prevent settlement and inhibit the growth of marine microorganisms for 2 months.